(See Section 8 "Exposure
Controls / Personal Protection" for exposure guidelines)
3. HAZARDS
IDENTIFICATION |
CHRONIC EFFECT
No chronic health effects are known to be associated with
exposure to continuous filament fiber glass. Results from epidemiologic studies have not
shown any increases in respiratory disease or cancer. The International Agency for
Research on Cancer (IARC) has classified continuous filament fiber glass as a Group 3
substance, not classifiable as to its carcinogenicity to humans. Because of their large
diameter, the continuous filament fibers in this product are not considered respirable.
|
TARGET ORGANS:
Respiratory Tract (nose & throat), Eyes, Skin
RESPIRATORY TRACT (nose & throat) IRRITATION:
Irritation of the upper respiratory tract (scratchy throat),
coughing, and congestion may occur in extreme exposures.
EYE IRRITATION:
May cause temporary, mild mechanical irritation. Fibers may be
abrasive; prolonged contact may cause damage to the outer surface of the eye.
SKIN IRRITATION:
May cause temporary, mild mechanical irritation. Exposure may
also result in inflammation, rash or itching.
GASTROINTESTINAL IRRITATION:
Unlikely route of exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
Pre-existing medical conditions, including dermatitis, asthma
or chronic lung disease may be aggravated by exposure; individuals who have a history of
allergies may experience greater amounts of skin and respiratory irritation. |
HAZARD CLASSIFICATION
The International Agency for Research on Cancer (IARC)
has classified continuous filament fiber glass as a Group 3 substance, not classifiable as
to its carcinogenicity to humans.
The Hazardous Materials Identification System (HMIS)
| Health 1 |
Flammability 0 |
Reactivity 0 |
Personal Protection Index: X (Employer
Determined) |
FIRST AID PROCEDURES
RESPIRATORY TRACT (nose & throat) IRRITATION:
If respiratory tract irritation develops, move the person to a
dust free location. Get medical attention if the irritation continues. See Section 8 for
additional measures to reduce or eliminate exposure.
EYE IRRITATION:
If eyes become irritated, flush immediately with large amounts
of lukewarm water for at least 15 minutes. Eyelids should be held away from the eyeball to
ensure thorough rinsing. Do not rub eyes. Get medical attention if irritation persists.
SKIN IRRITATION:
If skin becomes irritated, remove soiled clothing. Do not rub
or scratch exposed skin. Wash area of contact thoroughly with soap and water. Using a skin
cream or lotion after washing may be helpful.
GASTROINTESTINAL IRRITATION:
If gastrointestinal tract irritation develops, move the person
to a dust free environment.
NOTES TO PHYSICIANS:
Skin and respiratory effects are the result of temporary, mild
mechanical irritation; fiber exposure does not result in allergic manifestations.
5. FIRE
FIGHTING MEASURES |
| NFPA Codes: |
Flammability: 0 |
Health: 1 |
Reactivity: 0 |
Special: 0 |
NFPA Unusual Hazards: None
Flammable Properties: None
Flash Point: None
Hazardous Decomposition Products: Thermal decomposition
of binder from fires or from first heat of product may release smoke, carbon monoxide,
carbon dioxide, oxides of nitrogen and small amounts of aromatic and aliphatic
hydrocarbons. Use adequate ventilation or other precautions to eliminate exposure to
vapors resulting from thermal decomposition of binder. Exposure to thermal decomposition
fumes may cause respiratory tract irritation, bronchial hyper-reactivity or an
asthmatic-type response.
Unusual Fire and Explosion Hazard: None
Extinguishing Media: Use extinguishing media suitable
for type of surrounding fire.
6.
ACCIDENTAL RELEASE MEASURES |
SPILL PROCEDURES
Avoid creating airborne dust. Dust suppressing cleaning
methods such as wet sweeping or vacuuming should be used to clean the work area. If
vacuuming, the vacuum must be equipped with a HEPA filter. Compressed air or dry sweeping
should not be used for cleaning.
STORAGE
Store in original container in a dry area. Keep container
closed when not in use.
HANDLING
Handle fiber carefully. Limit use of power tools unless in
conjunction with local exhaust. Use hand tools whenever possible. Frequently clean the
work area with HEPA filtered vacuum or wet sweeping to minimize the accumulation of
debris. Do not use compressed air for clean-up.
EMPTY CONTAINERS
Product packaging may contain residue. Do not reuse.
8. EXPOSURE
CONTROLS/PERSONAL PROTECTION |
EXPOSURE GUIDELINES
| COMPONENTS |
OSHA PEL |
MANUFACTURER REG |
Fiberglass continuous filament fabric
Acrylic latex |
1 fiber/cc
None established |
None established
None established |
OTHER OCCUPATIONAL EXPOSURE LEVELS (OEL)
Non-regulatory OEL examples include: ACGIH TLVs: Fiberglass continuous
filament fabric -- 1 fiber/cc. Acrylic latex -- None established.
ENGINEERING CONTROLS
Use engineering controls such as local exhaust ventilation,
point of generation dust collection, down draft work stations, emission controlling tool
designs, and materials handling equipment designed to minimize airborne fiber emissions.
PERSONAL PROTECTION EQUIPMENT
Respiratory Protection:
When engineering and/or administrative controls are
insufficient, the use of appropriate respiratory protection, pursuant to the requirements
of OSHA Standards 29 CFR 1910.134 and 29 CFR 1926.103, is recommended. The following
information is provided as an example of appropriate respiratory protection for continuous
filament fibers. The evaluation of workplace hazards and the identification of appropriate
respiratory protection is best performed, on a case by case basis, by a qualified
Industrial Hygienist.
MANUFACTURER'S
RESPIRATORY PROTECTION RECOMMENDATIONS |
| Respirable Airborne Fiber Concentration |
Respirator Recommendation |
| Less than 1 f/cc |
No specific recommendation. User preference
based upon conditions present |
| 1 f/cc to 10 f/cc |
Half-face, air purifying respirator equipped
with a NIOSH approved P100 particulate filter cartridge |
| 50 f/cc to 100 f/cc |
Full-facepiece, air purifying respirator
equipped with a NIOSH approved P100 particulate filter cartridge |
The P100
recommendation is a conservative default choice; in some case, solid arguments can be made
that other respirator types (e.g., N95, R99, etc.) may be suitable for some tasks or work
environments. The P100 recommendation is not designed to limit informed choices, provided
that respiratory protection decisions comply with 29 CFR 1910.134.
Other Information:
- Concentrations based upon an eight-hour time weighted
average (TWA) as determined by air samples collected and analyzed pursuant to NIOSH method
7400 (B) for airborne fibers.
- Potential exposure to other airborne contaminants should be
evaluated by a qualified Industrial Hygienist; the selection of appropriate respiratory
protection and air monitoring depend upon the conditions present in the work environment.
Skin Protection:
Wear gloves, head coverings and full body clothing as
necessary to prevent skin irritation. Washable or disposable clothing may be used. If
possible, do not take unwashed clothing home. If soiled work clothing must be taken home,
employers should ensure employees are thoroughly trained on the best practices to minimize
or avoid non-work dust exposure (e.g., vacuum clothes before leaving the work area, wash
work clothing separately, rinse washer before washing other household clothes, etc.).
Eye Protection:
Wear safety glasses with side shields or other forms of eye
protection in compliance with appropriate OSHA standards to prevent eye irritation. The
use of contact lenses is not recommended, unless used in conjunction with appropriate eye
protection. Do not touch eyes with soiled body parts or materials. If possible, have
eye-washing facilities readily available where eye irritation can occur.
9. PHYSICAL
AND CHEMICAL PROPERTIES |
| ODOR AND APPEARANCE: |
White, odorless, fibrous material |
| CHEMICAL FAMILY: |
Continuous filament fiberglass |
| BOILING POINT: |
Not Applicable |
| WATER SOLUBILITY (%): |
Not Soluble in Water |
| MELTING POINT: |
Not Applicable |
| SPECIFIC GRAVITY: |
Not Applicable |
| VAPOR PRESSURE: |
Not Applicable |
| pH: |
Not Applicable |
| VAPOR DENSITY (Air = 1): |
Not Applicable |
| % VOLATILE: |
Not Applicable |
| MOLECULAR FORMULA: |
Not Applicable |
10.
STABILITY AND REACTIVITY |
| CHEMICAL STABILITY: |
Stable under conditions of normal use. |
| INCOMPATIBILITY: |
Soluble in hydrofluoric acid, phosphoric acid,
and concentrated alkali. |
| CONDITIONS TO AVOID: |
None. |
| HAZARDOUS DECOMPOSITION PRODUCTS: |
Thermal decomposition of binder from fires or
from first heat of product may release smoke, carbon monoxide, carbon dioxide, oxides of
nitrogen and small amounts of aromatic and aliphatic hydrocarbons. Use adequate
ventilation or other precautions to eliminate exposure to vapors resulting from thermal
decomposition of binder. Exposure to thermal decomposition fumes may cause respiratory
tract irritation, bronchial hyper-reactivity or an asthmatic-type response. |
| HAZARDOUS POLYMERIZATION: |
Not Applicable. |
11.
TOXICOLOGICAL INFORMATION |
EPIDEMIOLOGY
In 2001, the University of Pittsburgh finalized and published
the results of a historical cohort (1946-1992) study of U.S. fiber glass workers. This
study represented the world's largest (32,110 workers) and most comprehensive
investigation (more than a million persons-years of observation) of long-term health
effects of exposure to all types of glass fibers. This study found no increase in
mesotheliomas, no increase in non malignant respiratory disease (lung scarring), and no
significant increase in respiratory system cancer. There was no relationship between
respiratory system cancer and either duration of exposure or time since first exposure.
These results are generally similar to other cohort studies conducted in the U.S., Canada
and Europe.
TOXICOLOGY
Biosoluble glass fibers (i.e., fibers that do not persist in the lung) were tested
extensively in chronic inhalation studies using laboratory rodents and did not cause any
mesotheliomas, lung scarring or lung cancer. In other fiber glass studies, animals exposed
by artificial means (e.g., implantation and injection) have shown development of tumors.
12.
ECOLOGICAL INFORMATION |
No ecological concerns have been identified.
13.
DISPOSAL CONSIDERATIONS |
WASTE MANAGEMENT
To prevent waste materials from becoming airborne during waste
storage, transportation and disposal, a covered container or plastic bagging is
recommended.
DISPOSAL
This product, as manufactured, is not classified as a
hazardous waste according to Federal regulations (40 CFR 261). Any processing, use,
alteration or chemical additions to the product, as purchased, may alter the disposal
requirements. Under Federal regulations, it is the waste generator's responsibility to
properly characterize a waste material, to determine if it is a "hazardous"
waste. Check local, regional, state or provincial regulations to identify all applicable
disposal requirements.
EUROPEAN UNION
Waste from this product is not classified as
"hazardous" or "special" under European Union regulations. Disposal is
permitted at landfills licensed for industrial waste.
14.
TRANSPORT INFORMATION |
U.S. DEPARTMENT OF TRANSPORTATION (DOT)
| Hazard Class: |
Not Regulated |
United Nations (UN) Number: |
Not Applicable |
| Labels: |
Not Applicable |
North America (NA) Number: |
Not Applicable |
| Placards: |
Not Applicable |
Bill of Lading: |
Product Name |
INTERNATIONAL
Canadian TDG Hazard Class & PIN: Not regulated
Not classified as dangerous goods under ADR (road), RID
(train) or IMDG (ship).
15.
REGULATORY INFORMATION |
UNITED STATES REGULATIONS
| EPA: |
Superfund Amendments and Reauthorization
Act (SARA) Title III - This product does not contain any substances reportable under
Sections 302, 304, 313, (40 CFR 372).
Toxic Substances Control Act (TSCA) - All substances in
this product are listed, as required, on the TSCA inventory.
Comprehensive Environmental Response, Compensation and
Liability Act (CERCLA) and the Clean Air Act (CAA) - This product
contains fibers with an average diameter greater than one micron and thus is not
considered a hazardous air pollutant. |
| OSHA: |
Comply with Hazard Communication Standards
29 CFR 1910.1200 and 29 CFR 1926.59 and the Respiratory Protection Standards 29 CFR
1910.134 and 29 CFR 1926.103. |
| States: |
This product is not known to be regulated by
any state; however, state and local OSHA and EPA regulations may apply to these products.
If in doubt, contact your local regulatory agency. |
INTERNATIONAL REGULATIONS
| Canada: |
Canadian Environmental Protection Act
(CEPA) - All substances in this product are listed, as required, on the Domestic
Substance List (DSL) |
PRODUCT STEWARDSHIP PROGRAM
The Unifrax Corporation has established a program to provide
customers with up-to-date information regarding the proper use and handling of this
product. In addition, Unifrax Corporation has also established a program to monitor
airborne fiber concentrations at customer facilities. If you would like more information
about this program, please call the Unifrax Corporation Product Stewardship Information
Hotline at 1-800-322-2293.
DEFINITIONS
| ACGIH: |
American Conference of Governmental Industrial
Hygienists |
| ADR: |
Carriage of Dangerous Goods by Road
(International Regulation) |
| CAA: |
Clean Air Act |
| CAS: |
Chemical Abstracts Service |
| CERCLA: |
Comprehensive Environmental Response,
Compensation and Liability Act |
| DSL: |
Domestic Substances List |
| EPA: |
Environmental Protection Agency |
| EU: |
European Union |
| f/cc: |
Fibers per cubic centimeter |
| HEPA: |
High Efficiency Particulate Air |
| HMIS: |
Hazardous Materials Identification System |
| IARC: |
International Agency for Research on Cancer |
| IATA: |
International Air Transport Association |
| IMDG: |
International Maritime Dangerous Goods Code |
| mg/m³: |
Milligrams per cubic meter of air |
| mmpcf: |
Million particles per cubic meter |
| NFPA: |
National Fire Protection Association |
| NIOSH: |
National Institute for Occupational Safety and
Health |
| OSHA: |
Occupational Safety and Health Administration |
| 29 CFR 1910.134 & 1926.103: |
OSHA Respiratory Protection Standards |
| 29 CFR 1910.1200 & 1926.59: |
OSHA Hazard Communication Standards |
| PEL: |
Permissible Exposure Limit (OSHA) |
| PIN: |
Product Identification Number |
| PNOC: |
Particulates Not Otherwise Classified |
| PNOR: |
Particulates Not Otherwise Regulated |
| PSP: |
Product Stewardship Program |
| RCRA: |
Resource Conservation and Recovery Act |
| REL: |
Recommended Exposure Limit (NIOSH) |
| RID: |
Carriage of Dangerous Goods by Rail
(International Regulations) |
| SARA: |
Superfund Amendments and Reauthorization Act |
| SARA Title III: |
Emergency Planning and Community Right to Know
Act |
| SARA Section 302: |
Extremely Hazardous Substances |
| SARA Section 304: |
Emergency Release |
| SARA Section 311: |
MSDS/List of Chemicals and Hazardous Inventory |
| SARA Section 312: |
Emergency and Hazardous Inventory |
| SARA Section 313: |
Toxic Chemicals and Release Reporting |
| STEL: |
Short Term Exposure Limit` |
| SVF: |
Synthetic Vitreous Fiber |
| TDG: |
Transportation of Dangerous Goods |
| TLV: |
Threshold Limit Value (ACGIH) |
| TSCA: |
Toxic Substances Control Act |
| TWA: |
Time Weighted Average |
| WHMIS: |
Workplace Hazardous Materials Information
System (Canada) |
Revision Summary: Revises 09/18/97 MSDS. Substantial
revision due to reappraisal of fiber classification.
MSDS Prepared By: UNIFRAX RISK MANAGEMENT DEPARTMENT
DISCLAIMER
The information presented herein is presented in good faith
and believed to be accurate as of the effective date of this Material Safety Data Sheet.
Employers may use this MSDS to supplement other information gathered by them in their
efforts to assure the health and safety of their employees and the proper use of the
product. This summary of the relevant data reflects professional judgment; employers
should note that information perceived to be less relevant has not been included in this
MSDS. Therefore, given the summary nature of this document, Unifrax Corporation does not
extend any warranty (expressed or implied), assume any responsibility, or make any
representation regarding the completeness of this information or its suitability for the
purposes envisioned by the user.